Plymouth will start their new League Two campaign with a trip to Southend on August 3.
Last season's Capital One Cup finalists Bradford City face a trip to Huddersfield Town in the first round of the 2013-14 competition.
Plymouth have made Lewis Alessandra their second signing of the summer, with the striker penning a two year deal at Home Park.
Plymouth are keen to re-sign Yeovil striker Reuben Reid on loan, Glovers boss Gary Johnson has revealed.
Plymouth boss John Sheridan believes it's 50-50 whether player of the year Onismor Bhasera will re-sign for the League Two club.
Plymouth goalkeeper Jake Cole cannot wait for pre-season to get underway after signing a new one-year contract at the club.
Conor Hourihane, who captained Plymouth to Football League safety last season, has signed a new two-year deal with the club.
Plymouth apprentice Ben Purrington has signed his first professional contract with the Pilgrims.